Silk

Silk is a natural protein fiber, some forms of which can be woven into textiles. The protein fiber of silk is composed mainly of fibroin and is produced by certain insect larvae to form cocoons. The best-known silk is obtained from the cocoons of the larvae of the mulberry silkworm Bombyx mori reared in captivity (sericulture). The shimmering appearance of silk is due to the triangular prism-like structure of the silk fibre, which allows silk cloth to refract incoming light at different angles, thus producing different colors.

Silk is produced by several insects, but generally only the silk of moth caterpillars has been used for textile manufacturing. There has been some research into other types of silk, which differ at the molecular level. Silk is mainly produced by the larvae of insects undergoing complete metamorphosis, but some adult insects such as webspinners also produce silk, and some insects such as raspy crickets produce silk throughout their lives. Silk production also occurs in Hymenoptera (bees, wasps, and ants), silverfish, mayflies, thrips, leafhoppers, beetles, lacewings, fleas, flies, and midges. Other types of arthropod produce silk, most notably various arachnids such as spiders (see spider silk).

Etymology
The word silk comes from Old English sioloc, from Greek σηρικός serikos, "silken", ultimately from an Asian source (cf. Chinese si "silk", Manchurian sirghe, Mongolian sirkek).

Wild silk


Several kinds of wild silk, which are produced by caterpillars other than the mulberry silkworm, have been known and used in China, South Asia, and Europe since ancient times. However, the scale of production was always far smaller than for cultivated silks. There are several reasons for this: firstly, they differ from the domesticated varieties in colour and texture and are therefore less uniform; secondly, cocoons gathered in the wild have usually had the pupa emerge from them before being discovered so the silk thread that makes up the cocoon has been torn into shorter lengths; and thirdly, many wild cocoons are covered in a mineral layer that stymies attempts to reel from them long strands of silk. Thus, previously, the only way to obtain silk suitable for spinning into textiles in areas where commercial silks are not cultivated was by tedious and labor-intensive carding.

Commercial silks originate from reared silkworm pupae, which are bred to produce a white-colored silk thread with no mineral on the surface. The pupae are killed by either dipping them in boiling water before the adult moths emerge or by piercing them with a needle. These factors all contribute to the ability of the whole cocoon to be unravelled as one continuous thread, permitting a much stronger cloth to be woven from the silk. Wild silks also tend to be more difficult to dye than silk from the cultivated silkworm. A technique known as demineralizing allows the mineral layer around the cocoon of wild silk moths to be removed, leaving only variability in color as a barrier to creating a commercial silk industry based on wild silks in the parts of the world where wild silk moths thrive, such as in Africa and South America.

Genetic modification of domesticated silkworms is used to facilitate the production of more useful types of silk.

China
Silk fabric was first developed in ancient China. The earliest example of silk fabric is from 3630 BC, and it was used as wrapping for the body of a child from a Yangshao site in Qingtaicun at Xingyang, Henan.

Legend gives credit for developing silk to a Chinese empress, Leizu (Hsi-Ling-Shih, Lei-Tzu). Silks were originally reserved for the Emperors of China for their own use and gifts to others, but spread gradually through Chinese culture and trade both geographically and socially, and then to many regions of Asia. Because of its texture and lustre, silk rapidly became a popular luxury fabric in the many areas accessible to Chinese merchants. Silk was in great demand, and became a staple of pre-industrial international trade. In July 2007, archaeologists discovered intricately woven and dyed silk textiles in a tomb in Jiangxi province, dated to the Eastern Zhou Dynasty roughly 2,500 years ago. Although historians have suspected a long history of a formative textile industry in ancient China, this find of silk textiles employing "complicated techniques" of weaving and dyeing provides direct evidence for silks dating before the Mawangdui-discovery and other silks dating to the Han Dynasty (202 BC-220 AD).

Silk is described in a chapter on mulberry planting by Si Shengzhi of the Western Han (206 BC – 9 AD). There is a surviving calendar for silk production in an Eastern Han (25–220 AD) document. The two other known works on silk from the Han period are lost. The first evidence of the silk trade is the finding of silk in the hair of an Egyptian mummy of the 21st dynasty, c.1070 BC. The silk trade reached as far as the Indian subcontinent, the Middle East, Europe, and North Africa. This trade was so extensive that the major set of trade routes between Europe and Asia came to be known as the Silk Road.

The Emperors of China strove to keep knowledge of sericulture secret to maintain the Chinese monopoly. Nonetheless sericulture reached Korea with technological aid from China around 200 BC, the ancient Kingdom of Khotan by AD 50, and India by AD 140.

In the ancient era, silk from China was the most lucrative and sought-after luxury item traded across the Eurasian continent, and many civilizations, such as the ancient Persians, benefited economically from trade.

India
Silk has a long history in India. It is known as "Paat" in eastern India, Pattu in southern parts of India, and Resham in north India. Recent archaeological discoveries in Harappa and Chanhu-daro suggest that sericulture, employing wild silk threads from native silkworm species, existed in South Asia during the time of the Indus Valley Civilization dating between 2450 BC and 2000 BC, while "hard and fast evidence" for silk production in China dates back to around 2570 BC. Shelagh Vainker, a silk expert at the Ashmolean Museum in Oxford, who sees evidence for silk production in China "significantly earlier" than 2500–2000 BC, suggests, "people of the Indus civilization either harvested silkworm cocoons or traded with people who did, and that they knew a considerable amount about silk."

India is the second largest producer of silk in the world after China. About 97% of the raw silk comes from five Indian states, namely, Andhra Pradesh, Karnataka, Jammu and Kashmir, Tamil Nadu and West Bengal. North Bangalore, the upcoming site of a $20 million "Silk City" Ramanagara and Mysore, contribute to a majority of silk production in Karnataka.

In Tamil Nadu, mulberry cultivation is concentrated in the Coimbatore, Erode, Tiruppur, Salem and Dharmapuri districts. Hyderabad, Andhra Pradesh, and Gobichettipalayam, Tamil Nadu, were the first locations to have automated silk reeling units in India.

India is also the largest consumer of silk in the world. The tradition of wearing silk sarees for marriages and other auspicious ceremonies is a custom in Assam and southern parts of India. Silk is considered to be a symbol of royalty, and, historically, silk was used primarily by the upper classes. Silk garments and sarees produced in Kanchipuram, Pochampally, Dharmavaram, Mysore, Arani in the south, Banaras in the north, and Murshidabad in the east are well recognized. In the northeastern state of Assam, three different types of silk are produced, collectively called Assam silk: Muga, Eri and Pat silk. Muga, the golden silk, and Eri are produced by silkworms that are native only to Assam.

Thailand
Silk is produced year round in Thailand by two types of silkworms, the cultured Bombycidae and wild Saturniidae. Most production is after the rice harvest in the southern and northeastern parts of the country. Women traditionally weave silk on hand looms and pass the skill on to their daughters, as weaving is considered to be a sign of maturity and eligibility for marriage. Thai silk textiles often use complicated patterns in various colours and styles. Most regions of Thailand have their own typical silks. A single thread filament is too thin to use on its own so women combine many threads to produce a thicker, usable fiber. They do this by hand-reeling the threads onto a wooden spindle to produce a uniform strand of raw silk. The process takes around 40 hours to produce a half kilogram of silk. Many local operations use a reeling machine for this task, but some silk threads are still hand-reeled. The difference is that hand-reeled threads produce three grades of silk: two fine grades that are ideal for lightweight fabrics, and a thick grade for heavier material.

The silk fabric is soaked in extremely cold water and bleached before dyeing to remove the natural yellow coloring of Thai silk yarn. To do this, skeins of silk thread are immersed in large tubs of hydrogen peroxide. Once washed and dried, the silk is woven on a traditional hand-operated loom.

Ancient Mediterranean
In the Odyssey, 19.233, when Odysseus, while pretending to be someone else, is questioned by Penelope about her husband's clothing, he says that he wore a shirt "gleaming like the skin of a dried onion" (varies with translations, literal translation here) which could refer to the lustrous quality of silk fabric. The Roman Empire knew of and traded in silk, and Chinese silk was the most highly priced luxury good imported by them. During the reign of emperor Tiberius, sumptuary laws were passed that forbade men from wearing silk garments, but these proved ineffectual. Despite the popularity of silk, the secret of silk-making only reached Europe around AD 550, via the Byzantine Empire. Legend has it that monks working for the emperor Justinian I smuggled silkworm eggs to Constantinople in hollow canes from China. All top-quality looms and weavers were located inside the Great Palace complex in Constantinople, and the cloth produced was used in imperial robes or in diplomacy, as gifts to foreign dignitaries. The remainder was sold at very high prices.

Middle East
In the Torah, a scarlet cloth item called in Hebrew "sheni tola'at" שני תולעת - literally "crimson of the worm" - is described as being used in purification ceremonies, such as those following a leprosy outbreak (Leviticus 14), alongside cedar wood and hyssop (za'atar). Eminent scholar and leading medieval translator of Jewish sources and books of the Bible into Arabic, Rabbi Saadia Gaon, translates this phrase explicitly as "crimson silk" - חריר קרמז حرير قرمز.

In Islamic teachings, Muslim men are forbidden to wear silk. Many religious jurists believe the reasoning behind the prohibition lies in avoiding clothing for men that can be considered feminine or extravagant. There are disputes regarding the amount of silk a fabric can consist of (e.g., whether a small decorative silk piece on a cotton caftan is permissible or not) for it to be lawful for men to wear, but the dominant opinion of most Muslim scholars is that the wearing of silk by men is forbidden. Modern attire has raised a number of issues, including, for instance, the permissibility of wearing silk neckties, which are masculine articles of clothing.

Despite injunctions against silk for men, silk has retained its popularity in the Islamic world because of its permissibility for women, and due to the presence of non-Muslim communities. The Muslim Moors brought silk with them to Spain during their conquest of the Iberian Peninsula.

Medieval and modern Europe


Italy was the most important producer of silk during the Medieval age. The first center to introduce silk production to Italy was the city of Catanzaro during the 11th century in the region of Calabria. The silk of Catanzaro supplied almost all of Europe and was sold in a large market fair in the port of Reggio Calabria, to Spanish, Venetian, Genovese and Dutch merchants. Catanzaro became the lace capital of the world with a large silkworm breeding facility that produced all the laces and linens used in the Vatican. The city was world-famous for its fine fabrication of silks, velvets, damasks and brocades.

Another notable center was the Italian city-state of Lucca which largely financed itself through silk-production and silk-trading, beginning in the 12th century. Other Italian cities involved in silk production were Genoa, Venice and Florence.

The Silk Exchange in Valencia from the 15th century—where previously in 1348 also perxal (percale) was traded as some kind of silk—illustrates the power and wealth of one of the great Mediterranean mercantile cities.

Silk was produced in and exported from the province of Granada, Spain, especially the Alpujarras region, until the Moriscos, whose industry it was, were expelled from Granada in 1571.

Since the 15th century, silk production in France has been centered around the city of Lyon where many mechanic tools for mass production were first introduced in the 17th century. James I attempted to establish silk production in England, purchasing and planting 100,000 mulberry trees, some on land adjacent to Hampton Court Palace, but they were of a species unsuited to the silk worms, and the attempt failed. In 1732 John Guardivaglio set up a silk throwing enterprise at Logwood mill in Stockport; in 1744, Burton Mill was erected in Macclesfield; and in 1753 Old Mill was built in Congleton. These three towns remained the centre of the English silk throwing industry until silk throwing was replaced by silk waste spinning. British enterprise also established silk filature in Cyprus in 1928. In England in the mid-20th century, raw silk was produced at Lullingstone Castle in Kent. Silkworms were raised and reeled under the direction of Zoe Lady Hart Dyke. Production started elsewhere later.



North America
King James I introduced silk-growing to the American colonies around 1619, ostensibly to discourage tobacco planting. The Shakers in Kentucky adopted the practice. In the 19th century a new attempt at a silk industry began with European-born workers in Paterson, New Jersey, and the city became a silk center in the United States. Manchester, Connecticut emerged as center of the silk industry in America from the late 19th through the mid-20th century. The Cheney Brothers Historic District showcases mills refurbished as apartments and includes nearby museums.

World War II interrupted the silk trade from Asia, and silk prices increased dramatically. U.S. industry began to look for substitutes, which led to the use of synthetics such as nylon. Synthetic silks have also been made from lyocell, a type of cellulose fiber, and are often difficult to distinguish from real silk (see spider silk for more on synthetic silks).

Malaysia
In Terengganu, which is now part of Malaysia, a second generation of silkworm was being imported as early as 1764 for the country's silk textile industry, especially songket. However, since the 1980s, Malaysia is no longer engaged in sericulture but does plant mulberry trees.

Vietnam
In Vietnamese legend, silk appeared in the sixth dynasty of Hung Vuong.

Production process
The entire production process of silk can be divided into several steps which are typically handled by different entities. Extracting raw silk starts by cultivating the silkworms on mulberry leaves. Once the worms start pupating in their cocoons, these are dissolved in boiling water in order for individual long fibres to be extracted and fed into the spinning reel.

Physical properties
Silk fibers from the Bombyx mori silkworm have a triangular cross section with rounded corners, 5–10 μm wide. The fibroin-heavy chain is composed mostly of beta-sheets, due to a 59-mer amino acid repeat sequence with some variations. The flat surfaces of the fibrils reflect light at many angles, giving silk a natural sheen. The cross-section from other silkworms can vary in shape and diameter: crescent-like for Anaphe and elongated wedge for tussah. Silkworm fibers are naturally extruded from two silkworm glands as a pair of primary filaments (brin), which are stuck together, with sericin proteins that act like glue, to form a bave. Bave diameters for tussah silk can reach 65 μm. See cited reference for cross-sectional SEM photographs. Silk has a smooth, soft texture that is not slippery, unlike many synthetic fibers.

Silk is one of the strongest natural fibers, but it loses up to 20% of its strength when wet. It has a good moisture regain of 11%. Its elasticity is moderate to poor: if elongated even a small amount, it remains stretched. It can be weakened if exposed to too much sunlight. It may also be attacked by insects, especially if left dirty.

One example of the durable nature of silk over other fabrics is demonstrated by the recovery in 1840 of silk garments from a wreck of 1782: 'The most durable article found has been silk; for besides pieces of cloaks and lace, a pair of black satin breeches, and a large satin waistcoat with flaps, were got up, of which the silk was perfect, but the lining entirely gone ... from the thread giving way ... No articles of dress of woollen cloth have yet been found.'

Silk is a poor conductor of electricity and thus susceptible to static cling.

Unwashed silk chiffon may shrink up to 8% due to a relaxation of the fiber macrostructure, so silk should either be washed prior to garment construction, or dry cleaned. Dry cleaning may still shrink the chiffon up to 4%. Occasionally, this shrinkage can be reversed by a gentle steaming with a press cloth. There is almost no gradual shrinkage nor shrinkage due to molecular-level deformation.

Natural and synthetic silk is known to manifest piezoelectric properties in proteins, probably due to its molecular structure.

Silkworm silk was used as the standard for the denier, a measurement of linear density in fibers. Silkworm silk therefore has a linear density of approximately 1 den, or 1.1 dtex.

Chemical properties
Silk emitted by the silkworm consists of two main proteins, sericin and fibroin, fibroin being the structural center of the silk, and serecin being the sticky material surrounding it. Fibroin is made up of the amino acids Gly-Ser-Gly-Ala-Gly-Ala and forms beta pleated sheets. Hydrogen bonds form between chains, and side chains form above and below the plane of the hydrogen bond network.

The high proportion (50%) of glycine allows tight packing. This is because glycine's R group is only a hydrogen and so is not as sterically constrained. The addition of alanine and serine makes the fibres strong and resistant to breaking. This tensile strength is due to the many interceded hydrogen bonds, and when stretched the force is applied to these numerous bonds and they do not break.

Silk is resistant to most mineral acids, except for sulfuric acid, which dissolves it. It is yellowed by perspiration. Chlorine bleach will also destroy silk fabrics.

Uses


Silk's absorbency makes it comfortable to wear in warm weather and while active. Its low conductivity keeps warm air close to the skin during cold weather. It is often used for clothing such as shirts, ties, blouses, formal dresses, high fashion clothes, lining, lingerie, pajamas, robes, dress suits, sun dresses and Eastern folk costumes. For practical use, silk is excellent as clothing that protects from many biting insects that would ordinarily pierce clothing, such as mosquitoes. Silk's attractive lustre and drape makes it suitable for many furnishing applications. It is used for upholstery, wall coverings, window treatments (if blended with another fiber), rugs, bedding and wall hangings. While on the decline now, due to artificial fibers, silk has had many industrial and commercial uses, such as in parachutes, bicycle tires, comforter filling and artillery gunpowder bags.

Fabrics that are often made from silk include charmeuse, habutai, chiffon, taffeta, crepe de chine, dupioni, noil, tussah, and shantung, among others.

A special manufacturing process removes the outer irritant sericin coating of the silk, which makes it suitable as non-absorbable surgical sutures. This process has also recently led to the introduction of specialist silk underclothing for people with eczema where it can significantly reduce it. New uses and manufacturing techniques have been found for silk for making everything from disposable cups to drug delivery systems and holograms. To produce 1 kg of silk, 104 kg of mulberry leaves must be eaten by 3000 silkworms. It takes about 5000 silkworms to make a pure silk kimono. The production of silk is called sericulture. The major silk producers are China (54%) and India (14%).

Cultivation
Silk moths lay eggs on specially prepared paper. The eggs hatch and the caterpillars (silkworms) are fed on fresh mulberry leaves. After about 35 days and 4 moltings, the caterpillars are 10,000 times heavier than when hatched and are ready to begin spinning a cocoon. A straw frame is placed over the tray of caterpillars, and each caterpillar begins spinning a cocoon by moving its head in a pattern. Two glands produce liquid silk and force it through openings in the head called spinnerets. Liquid silk is coated in sericin, a water-soluble protective gum, and solidifies on contact with the air. Within 2–3 days, the caterpillar spins about 1 mile of filament and is completely encased in a cocoon. The silk farmers then kill most caterpillars by heat, leaving some to metamorphose into moths to breed the next generation of caterpillars. Harvested cocoons are then soaked in boiling water to soften the sericin holding the silk fibers together in a cocoon shape. The fibers are then unwound to produce a continuous thread. Since a single thread is too fine and fragile for commercial use, anywhere from three to ten strands are spun together to form a single thread of silk.

Animal rights
As the process of harvesting the silk from the cocoon kills the larvae, sericulture has been criticized by animal welfare and rights activists. Mohandas Gandhi was critical of silk production based on the Ahimsa philosophy which led to promotion of cotton and Ahimsa silk, a type of wild silk made from the cocoons of wild and semi-wild silk moths. Due to the death that silk production inflicts on the silkworms, People for the Ethical Treatment of Animals (PETA) urges people not to buy silk items.