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Plastic recycling

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Plastic recycling is the process of recovering scrap or waste plastic and reprocessing the material into useful products, sometimes completely different in form from their original state. For instance, this could mean melting down soft drink bottles and then casting them as plastic chairs and tables. However, this kind of "recycling" is rather a misnomer since plastic beverage bottles (soda, juice, milk) are never truly reformed into new beverage bottles, as this requires virgin plastic. So there is actually no true cycle in the "recycling" of plastic beverage containers, which actually and more precisely should be referred to as "downcycling".

Plastics are also recycled during the manufacturing process of plastic goods such as polyethylene film and bags. A percentage of the recycled pellets are then re-introduced into the main production operation. This closed-loop operation has taken place since the 1970s and has made the production of some plastic products amongst the most efficient operations today.

recycling one ton of plastic can save 5,774 Kwh of energy, 16.3 barrels of oil, 98,000,000 Btu's of energy, and 30 cubic yards of landfill space, 48,000 gallons of  H2O, 3/2 tons of CO2 a year, 245/594 tons of AlO2, 2,887/1,600,000 tons of Au, 2,887/25,000 tons of S, gain almost 65/8 tons of O per year

Challenges[]

Compared with lucrative recycling of materials, such as glass and metal, plastic polymers recycling is often more challenging because of low density and low value. There are also numerous technical hurdles to overcome when recycling plastic.

A macro molecule interacts with its environment along its entire length, so total energy involved in mixing it is largely due to the product side stoichiometry (see enthalpy). Heating alone is not enough to dissolve such a large molecule, so plastics must often be of nearly identical composition to mix efficiently.

When different types of plastics are melted together, they tend to phase-separate, like oil and water, and set in these layers. The phase boundaries cause structural weakness in the resulting material, meaning that polymer blends are useful in only limited applications.

Another barrier to recycling is the widespread use of dyes, fillers, and other additives in plastics. The polymer is generally too viscous to economically remove fillers, and would be damaged by many of the processes that could cheaply remove the added dyes. Additives are less widely used in beverage containers and plastic bags, allowing them to be recycled more often. Yet another barrier to removing large quantities of plastic from the waste stream and landfills is the fact that many common but small plastic items lack the universal triangle recycling symbol and accompanying number. An example is the billions of plastic utensils commonly distributed at fast food restaurants or sold for use at picnics.Template:Fix/category[citation needed]

The percentage of plastic that can be fully recycled, rather than downcycled or go to waste can be increased when manufacturers of packaged goods minimize mixing of packaging materials and eliminate contaminants. The Association of Plastics Recyclers have issued a Design Guide for Recyclability.[1]

The use of biodegradable plastics is increasing.[2]

Processes[]

Before recycling, most plastics are sorted according to their resin type. In the past, plastic reclaimers used the resin identification code (RIC), a method of categorization of polymer types, which was developed by the Society of the Plastics Industry in 1988. Polyethylene terephthalate, commonly referred to as PET, for instance, has a resin code of 1. Most plastic reclaimers do not rely on the RIC now; they use automatic sort systems to identify the resin, such as near infrared (NIR) technology. Some plastic products are also separated by color before they are recycled. The plastic recyclables are then shredded. These shredded fragments then undergo processes to eliminate impurities like paper labels. This material is melted and often extruded into the form of pellets which are then used to manufacture other products.

Thermal depolymerization[]

Main article: Depolymerization

Another process involves the conversion of assorted polymers into petroleum by a much less precise thermal depolymerization process. Such a process would be able to accept almost any polymer or mix of polymers, including thermoset materials such as vulcanized rubber tire superation of wastes and the biopolymers in feathers and other agricultural waste. Like natural petroleum, the chemicals produced can be made into fuels as well as polymers. A pilot plant of this type exists in Carthage, Missouri, United States, using turkey waste as input material. Gasification is a similar process, but is not technically recycling, since polymers are not likely to become the result.

Heat compression[]

Yet another process that is gaining ground with startup companies (especially in Australia, United States and Japan) is heat compression.Template:Fix/category[citation needed] The heat compression process takes all unsorted, cleaned plastic in all forms, from soft plastic bags to hard industrial waste, and mixes the load in tumblers (large rotating drums resembling giant clothes dryers). The most obvious benefit to this method is the fact that all plastic is recyclable, not just matching forms. However, criticism rises from the energy costs of rotating the drums, and heating the post-melt pipes.

Distributed Recycling[]

For some waste plastics, recent technical devices called recyclebots[3] enable a form of distributed recycling. Preliminary life-cycle analysis(LCA) indicates that such distributed recycling of HDPE to make filament of 3-D printers in rural regions is energetically favorable to either using virgin resin or conventional recycling processes because of reductions in transportation energy[4][5]

Other processes[]

A process has also been developed in which many kinds of plastic can be used as a C source in the recycling of scrap steel.[6]

Applications[]

PET[]

Main article: PET bottle recycling
File:Bales Crushed PET Bottles.JPG

Bales of PET bottles to be recycled.

Post-consumer polyethylene terephthalate (PET or PETE) containers are sorted into different colour fractions, and baled for onward sale. PET recyclers further sort the baled bottles and they are washed and flaked (or flaked and then washed). Non-PET fractions such as caps and labels are removed during this process. The clean flake is dried. Further treatment can take place e.g. melt filtering and pelletising or various treatments to produce food-contact-approved recycled PET (RPET).

RPET has been widely used to produce polyester fibres.[7] This sorted post-consumer PET waste is crushed, chopped into flakes, pressed into bales, and offered for sale.[8]

One use for this recycled PET that has recently started to become popular is to create fabrics to be used in the clothing industry.[9] The fabrics are created by spinning the PET flakes into thread and yarn.[8] This is done just as easily as creating polyester from brand new PET.[10] The recycled PET thread or yarn can be used either alone or together with other fibers to create a very wide variety of fabrics. Traditionally these fabrics are used to create strong, durable, rough, products, such as jackets, coat, shoes, bags, hats, and accessories since they are usually too rough for direct skin contact and can cause irritation.[11] However, these types of fabrics have become more popular as a result of the public's growing awareness of environmental issues. Numerous fabric and clothing manufacturers have capitalized on this trend.

Other major outlets for RPET are new containers (food-contact or non-food-contact) produced either by (injection stretch blow) moulding into bottles and jars or by thermoforming APET sheet to produce clam shells, blister packs and collation trays. These applications used 46% of all RPET produced in Europe in 2010.Template:Fix/category[citation needed] Other applications, such as strapping tape, injection-moulded engineering components and even building materials account for 13% of the 2010 RPET production.Template:Fix/category[citation needed]

In the United States the recycling rate for PET packaging was 31.2% in 2013, according to a report from The National Association for PET Container Resources (NAPCOR) and The Association of Postconsumer Plastic Recyclers (APR). A total of 1,798 million pounds was collected and 475 million pounds of recycled PET used out of a total of 5,764 million pounds of PET bottles.[12]

PVC[]

File:Resin-identification-code-3-V.svg

PVC SPI code, for recycling (Society of the Plastics Industry). The Unicode character for this symbol is U+2675.

Collection and recycling schemes for the PVC waste stream are managed through Recovinyl[13] in Europe which reported the recycled tonnage as follows: profile 107,000 tonnes; flexible cables 79,000 tonnes; pipe 25,000 tonnes; rigid film 6,000 tonnes; and mixed flexible 38,000 tonnes. Recovinyl states that of the recycled material, 75% is for floors, 15% for foils, 5% for traffic cones, 3% for hoses and 2% for other applications.

One of the recycling processes is the Vinyloop Texyloop[14] used for solvent-based mechanical recycling. It involves recovering PVC plastic from composite materials through dissolution and precipitation, and is a closed-loop system, recycling the solvent and regenerating PVC. It offers a major ecological benefit, as Vinyloop-based recycled PVC's primary energy demand is 46% lower than conventional produced PVC. The global warming potential of recycled PVC is 39% lower, a significant reduction in the ecological footprint.[15]

recycling one ton of PVC would save 120 kilograms of CO2, 125/44 grams of coal/Fe, 3,650/4,433 kwh of energy, 730/31,031 metric tons of Pb, a 219/88,660 cubic meter lake, keep 73/354,640 pounds of Hg out of landfills a year, 9,125/106,392 tons of waste, 163,155/2,030,314 gallons of oil, 365/8,866 metric tons of limestone, 96 square meters of natural habitat potential, 125/3,036 pounds of steam, 40 kilograms of fossil fuels, 288 kilograms of life, 12/191 metric tons of ethanol, 20/23 tons of soda ash, 17/5 kilograms of solid particles, 40/99 grams of Pd, 11/50 pounds of vinyl chloride, 1,320,000 btus of energy, enough energy to power over 51/3,500π cars for a year, a CFL for 73/32,032 weeks, a 100-watt light bulb for 73/160,160 weeks, almost $1,431.60

recycling one ton of virgin PVC could save 19/10 metric tons of CO2, 57/88 metric tons of coal, keep 1,387/20,150 tons of Hg out of landfills a year, 1,520 square meters of natural habitat potential, 2,375/506 tons of steam, 19/30 metric tons of fossil fuels, 114/25 metric tons of life, 190/191 metric tons of ethanol, 323/6 kilograms of solid particles, 950/69 tons of soda ash, 384/14,065 metric tons of W, enough energy to power over 323/1,400π cars for a year, a CFL for 380/13 years, a 100-watt light bulb for 76/13 years, almost $65,945.00

HDPE[]

Plastic # 2, high-density polyethylene (HDPE) is the most commonly recycled plastic. It is typically downcycled into plastic lumber, tables, roadside curbs, benches, truck cargo liners, trash receptacles, stationery (e.g. rulers) and other durable plastic products and is usually in demand.

PS[]

File:Resin-identification-code-6-PS.svg

The resin identification code symbol for polystyrene

Most polystyrene products are currently not recycled due to the lack of incentive to invest in the compactors and logistical systems required. As a result, manufacturers cannot obtain sufficient scrap. Expanded polystyrene (EPS) scrap can easily be added to products such as EPS insulation sheets and other EPS materials for construction applications. When it is not used to make more EPS, foam scrap can be turned into clothes hangers, park benches, flower pots, toys, rulers, stapler bodies, seedling containers, picture frames, and architectural molding from recycled PS.[16]

Recycled EPS is also used in many metal casting operations. Rastra is made from EPS that is combined with cement to be used as an insulating amendment in the making of concrete foundations and walls. Since 1993, American manufacturers have produced insulating concrete forms made with approximately 80% recycled EPS.

Other plastics[]

The white plastic polystyrene foam peanuts used as packing material are often accepted by shipping stores for reuse.[17]

Successful trials in Israel have shown that plastic films recovered from mixed municipal waste streams can be recycled into useful household products such as buckets.[18]

Similarly, agricultural plastics such as mulch film, drip tape and silage bags are being diverted from the waste stream and successfully recycled[19] into much larger products for industrial applications such as plastic composite railroad ties.[20] Historically, these agricultural plastics have primarily been either landfilled or burned on-site in the fields of individual farms.[21]

CNN reports that Dr. S. Madhu of the Kerala Highway Research Institute, India, has formulated a road surface that includes recycled plastic: aggregate, bitumen (asphalt) with plastic that has been shredded and melted at a temperature below 220 degrees C (428 °F) to avoid pollution. This road surface is claimed to be very durable and monsoon rain resistant. The plastic is sorted by hand, which is economical in India. The test road used 60 kg of plastic for an approximately 500m-long, 8m-wide, two-lane road. The process chops thin-film road-waste into a light fluff of tiny flakes that hot-mix plants can uniformly introduce into viscous bitumen with a customized dosing machine. Tests at both Bangalore and the Indian Road Research Centre indicate that roads built using this 'KK process' will have longer useful lives and better resistance to cold, heat, cracking, and rutting, by a factor of three.[22]

Recycling rates[]

The quantity of post-consumer plastics recycled has increased every year since at least 1990, but rates lag far behind those of other items, such as newspaper (about 80%) and corrugated fiberboard (about 70%).[23] Overall, U.S. post-consumer plastic waste for 2008 was estimated at 33.6 million tons; 2.2 million tons (6.5%) were recycled and 2.6 million tons (7.7%) were burned for energy; 28.9 million tons, or 85.5%, were discarded in landfills.[24]

Economic and energy potential[]

In 2008, the price of PET dropped from $370/ton in the US to $20 in November.[25] PET prices had returned to their long term averages by May 2009.[26] There has been an increase in the use of plastics over the past few decades. This increase in use has dried up various exhaustible resources and caused a threat to the environment. Plastic is a unique material to be used in a broad range of products again and again. Plastics use oil and energy during its manufacturing. Nearly 4% of oil in the world is used to manufacture plastic. Though this amount is not very large, recycling plastic will save this extinguishable energy source.[27]

Consumer education[]

United States[]

Low national plastic recycling rates have been due to the complexity of sorting and processing, unfavorable economics, and consumer confusion about which plastics can actually be recycled.[28] Part of the confusion has been due to the use of the resin identification code which is not on all plastic parts but just a subset[29] that includes the recycling symbol as part of its design. The resin identification code is stamped or printed on the bottom of containers and surrounded by a triangle of arrows. (See the table in Plastic.) The intent of these symbols was to make it easier to identify the type of plastics used to make a particular container and to indicate that the plastic is potentially recyclable. The question that remains is which types of plastics can be recycled by your local recycling center. In many communities, not all types of plastics are accepted for sidewalk recycling collection programs due to the high processing costs and complexity of the equipment required to recycle certain materials. There is also sometimes a seemingly low demand for the recycled product depending on a recycling center's proximity to entities seeking recycled materials. Another major barrier is that the cost to recycle certain materials and the corresponding market price for those materials sometimes does not present any opportunity for profit. The best example of this is polystyrene (commonly called styrofoam), although some communities, like Brookline, MA, are moving toward banning the distribution of polystyrene containers by local food and coffee businesses.[30][31]

United Kingdom[]

In the UK, the amount of post-consumer plastic being recycled is relatively low,[32] due in part to a lack of recycling facilities.

The Plastics 2020 Challenge was founded in 2009 by the plastics industry with the aim of engaging the British public in a nationwide debate about the use, reuse and disposal of plastics, and hosts a series of online debates on its website framed around the waste hierarchy.

There is a facility in Worksop capable of recycling 60 - 80 thousand metric tonnes a year.[33]

In N.Ireland, the rate of recycling is relatively low at only 37.4%. However, emerging technologies are helping to increase the recycling rates of items previously landfilled e.g. mixed hard plastics.[34]

Plastic identification code[]

Main article: Resin identification code

Five groups of plastic polymers,[35] each with specific properties, are used worldwide for packaging applications (see table below). Each group of plastic polymer can be identified by its Plastic Identification code (PIC), usually a number or a letter abbreviation. For instance, Low-Density Polyethylene can be identified by the number "4" or the letters "LDPE". The PIC appears inside a three-chasing-arrow recycling symbol. The symbol is used to indicate whether the plastic can be recycled into new products.Template:Fix/category[citation needed]

The PIC was introduced by the Society of the Plastics Industry, Inc., to provide a uniform system for the identification of various polymer types and to help recycling companies separate various plastics for reprocessing. Manufacturers of plastic products are required to use PIC labels in some countries/regions and can voluntarily mark their products with the PIC where there are no requirements.[36] Consumers can identify the plastic types based on the codes usually found at the base or at the side of the plastic products, including food/chemical packaging and containers. The PIC is usually not present on packaging films, since it is not practical to collect and recycle most of this type of waste.Template:Fix/category[clarification needed]Template:Fix/category[citation needed]

Plastic Identification Code Type of plastic polymer Properties Common Packaging Applications Glass Transition and Melting Temperatures (°C) Young's Modulus (GPa)
File:Plastic-recyc-01.svg
 Polyethylene terephthalate (PET, PETE) Clarity, strength, toughness, barrier to gas and moisture. Soft drink, water and salad dressing bottles; peanut butter and jam jars; small consumer electronics. Tm = 250;[37] Tg = 76[37] 2-2.7[38]
File:Plastic-recyc-02.svg
 High-density polyethylene (HDPE) Stiffness, strength, toughness, resistance to moisture, permeability to gas. Water pipes, hula hoop rings, five gallon buckets, milk, juice and water bottles; grocery bags, some shampoo/toiletry bottles. Tm = 130;[39] Tg = -125[40] 0.8[38]
File:Plastic-recyc-03.svg
 Polyvinyl chloride (PVC) Versatility, ease of blending, strength, toughness. Blister packaging for non-food items; cling films for non-food use. May be used for food packaging with the addition of the plasticisers needed to make natively rigid PVC flexible . Non-packaging uses are electrical cable insulation; rigid piping; vinyl records. Tm = 240;[41] Tg = 85[41] 2.4-4.1[42]
File:Plastic-recyc-04.svg
 Low-density polyethylene (LDPE) Ease of processing, strength, toughness, flexibility, ease of sealing, barrier to moisture. Frozen food bags; squeezable bottles, e.g. honey, mustard; cling films; flexible container lids. Tm = 120;[43] Tg = -125[44] 0.17-0.28[42]
File:Plastic-recyc-05.svg
 Polypropylene (PP) Strength, toughness, resistance to heat, chemicals, grease and oil, versatile, barrier to moisture. Reusable microwaveable ware; kitchenware; yogurt containers; margarine tubs; microwaveable disposable take-away containers; disposable cups; soft drink bottle caps; plates. Tm = 173;[45] Tg = -10[45] 1.5-2[38]
File:Plastic-recyc-06.svg
 Polystyrene (PS) Versatility, clarity, easily formed Egg cartons; packing peanuts; disposable cups, plates, trays and cutlery; disposable take-away containers. Tm = 240 (only isotactic);[40] Tg = 100 (atactic and isotactic)[40] 3-3.5[38]
File:Plastic-recyc-07.svg
 Other (often polycarbonate or ABS) Dependent on polymers or combination of polymers Beverage bottles; baby milk bottles. Non-packaging uses for polycarbonate: compact discs; "unbreakable" glazing; electronic apparatus housings; lenses including sunglasses, prescription glasses, automotive headlamps, riot shields, instrument panels.[46] Polycarbonate: Tg = 145;[47] Tm = 225[48] Polycarbonate: 2.6;[38] ABS plastics: 2.3[38]

See also[]

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References[]

  1. ↑ http://www.plasticsrecycling.org/images/pdf/market_development/APR_Design_Guide_Exec_Summary2014.pdf
  2. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  3. ↑ Christian Baechler, Matthew DeVuono, and Joshua M. Pearce, "Distributed Recycling of Waste Polymer into RepRap Feedstock" Rapid Prototyping Journal, 19(2), pp. 118-125 (2013). open access
  4. ↑ M. Kreiger, G. C. Anzalone, M. L. Mulder, A. Glover and J. M Pearce (2013). Distributed Recycling of Post-Consumer Plastic Waste in Rural Areas. MRS Online Proceedings Library, 1492, mrsf12-1492-g04-06 doi:10.1557/opl.2013.258. open access
  5. ↑ M.A. Kreiger, M.L. Mulder, A.G. Glover, J. M. Pearce, Life Cycle Analysis of Distributed Recycling of Post-consumer High Density Polyethylene for 3-D Printing Filament, Journal of Cleaner Production, 70, pp. 90–96 (2014). DOI:http://dx.doi.org/10.1016/j.jclepro.2014.02.009. open access
  6. ↑ Steel CNN. Retrieved 9.11.06.
  7. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  8. ↑ 8.0 8.1 Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  9. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  10. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  11. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  12. ↑ http://www.plasticstoday.com/articles/recycling-for-PET-packaging-reaches-31-percent-in-2013-141008
  13. ↑ Incentives to collect and recycle. Recovinyl. Retrieved on 2011-10-06.
  14. ↑ Texyloop : recyclage de textiles PVC. Texyloop.com. Retrieved on 2011-10-06.
  15. ↑ Vinyloop White Paper. Retrieved on 2014-01-11.
  16. ↑ Polystyrene recycling. Polystyrene packaging council. Retrieved on 2009-03-06.
  17. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  18. ↑ Plastic trial procedure Oaktech Environmental website. Retrieved 9.11.06.
  19. ↑ Agricultural plastics recycling process Agricultural plastics recycling website. Retrieved 07.11.08.
  20. ↑ Plastic Composite Railroad Tie Facts Plastic Composite Railroad Ties website. Retrieved 01.21.08.
  21. ↑ Recycling Used Agricultural Plastics James W. Garthe, Paula D. Kowal, PennState University, Agricultural and Biological Engineering
  22. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  23. ↑ The Self-Sufficiency Handbook: A Complete Guide to Greener Living by Alan Bridgewater pg. 62--Skyhorse Publishing Inc., 2007 ISBN 1-60239-163-7, ISBN 978-1-60239-163-5
  24. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  25. ↑ Page, Candace, Waste district raises recycling fees, Burlington Free Press, November 12, 2008
  26. ↑ Financial Times, May 15, 2009 (article by Max Hogg)
  27. ↑ http://www.almumayezplastic.com/aboutus
  28. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  29. ↑ SPI Resin Identification Code - Guide to Correct Use, http://www.plasticsindustry.org/AboutPlastics/content.cfm?ItemNumber=823
  30. ↑ Where can we put all those plastics? By Tom Watson June 2, 2007 Seattle Times http://seattletimes.nwsource.com/html/homegarden/2003730398_ecoconsumer02.html
  31. ↑ Brookline Town Meeting bans Styrofoam coffee, takeout containers by Brock Parker Nov 13, 2012 Boston.com http://www.boston.com/yourtown/news/brookline/2012/11/brookline_town_meeting_bans_st.html
  32. ↑ Plastics wasteonline.org.uk. Retrieved 10.18.07.
  33. ↑ http://www.mbapolymers.com/home/mba-polymers-uk-ltd
  34. ↑ http://www.envirogreenrecycling.com/plastic-recycling
  35. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  36. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  37. ↑ 37.0 37.1 [1] PolymerProcessing.com
  38. ↑ 38.0 38.1 38.2 38.3 38.4 38.5 [2] The Engineering Toolbox
  39. ↑ [3] Dyna Lab Corp
  40. ↑ 40.0 40.1 40.2 [4] Sigma Aldrich
  41. ↑ 41.0 41.1 [5] PolymerProcessing.com
  42. ↑ 42.0 42.1 Modern Plastics Encyclopedia 1999, p B158 to B216.(Tensile Modulus)
  43. ↑ [6] Dyna Lab Corp
  44. ↑ [7] Wofford University
  45. ↑ 45.0 45.1 [8] PolymerProcessing.com
  46. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  47. ↑ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Configuration' not found.
  48. ↑ [9] PolymerProcessing.com
  49. ↑ Cleaning soils with plastics by fungi

European Commission's funded FP7 project PRIME on mixed plastics recycling

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